Synthesis and Characterization of Dichlorotin(IV)trithiophosphates and Their Adducts with Nitrogen Donor Bases |
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| Authors: | Umesh N Tripathi Deepak K Sharma |
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| Institution: | School of Studies in Chemistry, Vikram University , Ujjain , India |
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| Abstract: | Abstract Dichlorotin(IV)trithiophosphates (RO)P(S)S 2 ]SnCl 2 were prepared by the reaction of methanolic solution of SnCl 4 and dipotassium salt of trithiophosphates in a 1:1 molar ratio and their adducts (RO)P(S)S 2 ]SnCl 2.N 2 C 12 H 8 and (RO)P(S)S 2 ]SnCl 2.N 2 C 10 H 8 were prepared by the reaction of methanolic solution of (RO)P(S)S 2 ]SnCl 2 and N-donor bases in a 1:1 molar ratio. These newly synthesised derivatives have been characterized by elemental analysis; molecular weight measurements; and IR, 13 C, 31 p and 119 Sn NMR spectral studies. Coordination number of four and six was suggested for dichlorotin (IV)trithiophosphates and their adducts with N-donor bases respectively. |
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| Keywords: | Phosphorotrithioate tin(IV) |
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