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Synthesis and Study of a Sulfur Heterocycle Fused p-Phenylene Vinylene Conducting Polymer
Authors:Martin Pomerantz  Jiping Wang  Seeyearl Seong  Kyle P Starkey  Long Nguyen  Dennis S Marynick
Institution:Center for Advanced Polymer Research, Department of Chemistry and Biochemistry , The University of Texas at Arlington , Box 19065, Arlington, Texas, 76019, USA
Abstract:Abstract

Poly(benzo1,2-b:4,5-b′]dithiophene-4,8-diyl vinylene) (1) has been prepared by the pyrolysis of the precursor polymer 2 and studied. Quantum mechanical calculations on the aromatic and quinoid monomers, oligomers and polymers indicate that 1 is a planar aromatic polymer.
Keywords:
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