New Dimethyl(Methylenoxyaryl)Phosphine Oxides |
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Authors: | S. Varbanov T. Tosheva G. Borisov |
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Affiliation: | Central Laboratory for Polymers, Bulgarian Academy of Sciences , Sofia , 1040 , Bulgaria |
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Abstract: | Abstract In the poster presentation is reported the preparation of the new dimethyl(methylenoxyaryl)phosphine oxides via ZVilliamson reaction from dimethyl-chloromethyl-phoaphine oxide and sodium solts of the coresponding phenols: l-di-methylphosphinylmethylenoxy-4-methyl-2,6-bis(l,l -dimethylethyl)benzene; 1,3-bis(dimethylphosphinylmethylenOxy)benzene; 1,4-bis(dimethylphosphinylmethylenoxy)ben-zene; 1,3,5-tris(dimethylphosphinylmethylenoxy)benzene; 1,2,3-tris(dimethylphosphinylmethylenoxy~benzene; 2,2′-methylene-bia(6-tert-butyl-4-methyl-l-dimethyl-phosphinylmethylenoxybenzene); 2,2′-rnethylene-bis-(6-tert-butyl-4-ethyl-l-dimethylphosphinylmethyleno~-benzene) and 1,1,3-tris(5-tert-butyl-4-dimethylphoa-phinylmethylenoxy-2-methyl-phenyl)butan. |
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