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Highly Selective Asymmetric Intramolecular Selenocyclisation
Authors:Hiroya Takada  Yoshiaki Nishibayashi  Sanjay Kumar Srivastava  Kouichi Ohe  Sakae Uemura
Abstract:Asymmetric intramolecular selenocyclisation of alkenoic acids, alkenols and alkenyl urethanes using chiral ferrocenylselenenyl cations proceeds smoothly to give the corresponding lactones, cyclic ethers and N-heterocyclic compounds, respectively, in moderate yields with very high diastereoselectivities.
Keywords:diselenide  selenocyclisation  alkenoic acids  alkenols  alkenyl urethanes
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