Phosphorylacetaladehydes in Reactions with N-Electro-Philes. Synthesis of new Promising Synthons |
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| Authors: | V. A. Pavlov V. V. Moskva B. I. Buzykin M. P. Sokolov B. G. Liorber N. V. Aristova |
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| Affiliation: | S.M. Kirov Institute of Chemical Technology , K. Marx St. 68, Kazan , 420015 , USSR |
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| Abstract: | Abstract The reactions of phosphorylacetaldehydes I with N-electro-philes (+NO, +N2Ar) proceed selectively via intermediate A in accordance with one of the three directions depending on the nature of the substituents X and R. The nature of the end product is determined by the competitive electrofugic power of R2P(O), X and CHO. |
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