1,1-Bis(Methylthio)-2-Nitroethene,a Versatile Synthon for the Synthesis of Oximinoorthothioesters |
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| Authors: | Jean-Marie Coustard Jean-Claude Jacquesy |
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| Institution: | Laboratoire de Chimie XII - URA CNRS 1468 , Faculté des Sciences , 40, Avenue du Recteur Pineau - 86022, Poitiers Cédex, France |
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| Abstract: | Abstract 1,1-bis(methylthio)-2-nitroethene gives a stable hydro-xynitrilium ion in trifluoromethanesulfonic acid. This cation can be trapped by various nucleophiles to yield a-oximinoorthothioesters. |
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