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Mössbauer study of Fe-substituted orthorhombic and tetragonal YBa2(Cu1-xFex)3O7-σ system
Authors:S N Shringi  O M Prakash  R V Vadnere  S Prasad  N Sharma
Institution:(1) Department of Physics, Indian Institute of Technology, 400 076 Bombay, India;(2) Materials Science Centre, Indian Institute of Technology, 400 076 Bombay, India
Abstract:Mössbauer study of orthorhombic and tetragonal YBa2(Cu1-xFex)3O7-σ;x=0.02, 0.04, 0.08 has been done to investigate the two inequivalent Cu-sites. Fe substituting Cu having pyramidal oxygen co-ordination is in Fe3+ state while Fe substituting Cu having square planar co-ordination is in Fe3+ and Fe4+ states in dynamic equilibrium.
Keywords:M?ssbauer effect  high temperature superconductivity  YBa2Cu3O7-σ  
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