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Enantioselective reduction of acetophenone analogues using carrot and celeriac enzymes system |
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| Authors: | Xiang Liu Zheng Guang Pan Jian He Xu He Xing Li |
| Institution: | a School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China;b State Key Laboratory of Bioreactor Engineering, East China University of Science and Technology, Shanghai 200237, China;c Department of Chemistry, Shanghai Normal University, Shanghai 200234, China |
| Abstract: | The enantioselective reduction of acetophenone analogues catalyzed by carrot and celeriac was performed in moderate conversions and excellent enantiomeric excesses.The steric factors and electronic effects of the substituents at the aromatic ring were found to significantly affect the efficiency of the enantioselective reduction of acetophenone analogues,while they had a little effect on the enantioselectivity of acetophenone analogues reduction.It was also found that the conversions of acetophenone analogu... |
| Keywords: | Enantioselective reduction Acetophenone analogues Plant cells Biocatalysis |
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