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Synthesis and the crystal structure of the supramolecular complex [Cl3InW3S4(H2O)9]2+ with cucurbituril
Authors:Sokolov  M. N.  Dybtsev  D. N.  Virovets  A. V.  Clegg  W.  Fedin  V. P.
Affiliation:(1) Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent"eva, 630090 Novosibirsk, Russian Federation;(2) Department of Chemistry, University of Newcastle, NE 7RU Newcastle upon Tyne, UK
Abstract:The supramolecular complex {[Cl3InW3S4(H2O)9]2(C36H36N24O12)}Cl4·28H2O was prepared by mixing solutions of [Cl3InW3S4(H2O)9]2+ and cucurbituril in hydrochloric acid. The molecular and crystal structure of the resulting complex was established by X-ray diffraction analysis.
Keywords:sulfide clusters  tungsten  indium  cucurbituril  crystal structure  supramolecular adduct
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