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Electrochemical methods for the determination of total arsenic and arsenic compounds
Authors:Herbert Greschonig  Kurt J Irgolic
Abstract:The determination of total arsenic and of arsenic compounds in biological and inorganic samples is a task frequently encountered by analysts. Several elecrochemical methods have been developed for the determination of total arsenic (generally after mineralization of the sample), arsenite, arsenate, methylarsonic acid and dimethylarsinic acid. The electrochemical behavior of several other organic arsenic compounds was also studied. This paper reviews these electrochemical methods, their application to environmental samples, and the problems encountered in the electrochemical determination of arsenic and arsenic compounds.
Keywords:Arsenic  arsenic compounds  electrochemical determination  polarography  stripping voltammetry
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