CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine |
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| Authors: | Christopher D Windle Marius V Câmpian Anne-K Duhme-Klair Elizabeth A Gibson Robin N Perutz Jacob Schneider |
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| Institution: | Department of Chemistry, University of York, York, YO10 5DD, United Kingdom. |
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| Abstract: | Photocatalytic CO(2) reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of Re(CO)(3)(Picoline)Bpy](+) and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad. |
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