Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire |
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| Authors: | Thomas Cadenbach Eva Hevia Alan R Kennedy Robert E Mulvey Janie-Anne Pickrell Stuart D Robertson |
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| Institution: | WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL, Scotland, UK. r.e.mulvey@strath.ac.uk stuart.d.robertson@strath.ac.uk. |
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| Abstract: | New coordination complexes of the neutral tripodal tetra-amine Me(6)TREN with tBu(3)Ga or tBu(2)Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an η(1) or η(2) mode, adding to previously reported η(3) and η(4) ligated examples. |
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