| Formation of a three-dimensional bispyridyl based metal-organic architecture containing unique Ag...Ag （d^10-d^10） interactions |
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| 作者姓名： | Xiao Ling Guo Yun Yin Niu Qing Li Wang Ben Lai Wu Hong Yun Zhang Hong Wei Hou Yi Han Ling Fang Wang |
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| 作者单位： | Department of Chemistry, Zhengzhou University, Henan 450052, China |
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| 基金项目： | This research was funded by Science Foundation for Distinguished Young Scholars of Henan Province(No.0412002800)and the NSFC(No.20671083). |
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| 摘 要： | A novel co-ordination polymer based on IB metal thiocyanates, Ag2（NCS）2（4,4＇-bipy）]. （1）（4,4＇-bipy = 4,4＇-bispyridine）, has been synthesized by the pre-assembly method and characterized by X-ray crystallography. The complex exists as a three- dimensional network consisting of （AgSCN）. undulating layers linked by 4,4＇-bipy bridges.
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| 关 键 词： | d^10-d^10交互作用 金属硫氰酸酯 晶体结构 超分子结构 分子结构 |
| 修稿时间： | 2007年10月10 |
Formation of a three-dimensional bispyridyl based metal–organic architecture containing unique Ag Ag (d–d) interactions |
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| Xiao Ling Guo Yun Yin Niu Qing Li Wang Ben Lai Wu Hong Yun Zhang Hong Wei Hou Yi Han Ling Fang Wang.Formation of a three-dimensional bispyridyl based metal–organic architecture containing unique AgAg (d–d) interactions[J].Chinese Chemical Letters,2008,19(5):604-606. |
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| Authors: | Xiao Ling Guo Yun Yin Niu Qing Li Wang Ben Lai Wu Hong Yun Zhang Hong Wei Hou Yi Han Ling Fang Wang |
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| Institution: | Department of Chemistry, Zhengzhou University, Henan 450052, China |
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| Abstract: | A novel co-ordination polymer based on IB metal thiocyanates,Ag_2(NCS)_2(4,4'-bipy)]_n(1)(4,4'-bipy=4,4'-bispyridine),has been synthesized by the pre-assembly method and characterized by X-ray crystallography.The complex exists as a three- dimensional network consisting of(AgSCN)_n undulating layers linked by 4,4'-bipy bridges. |
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| Keywords: | d~(10)-d~(10) interaction Metal thiocyanates Crystal structure Supramolecular structure Molecular structure |
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