Selective reduction of one, two, or three nitro groups in 1,3,5-trinitrobenzene with hydrazine hydrate |
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| Authors: | A. Kh. Shakhnes S. S. Vorob’ev S. A. Shevelev |
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| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation |
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| Abstract: | A method was developed for successive selective reduction of one, two, or three nitro groups in 1,3,5-trinitrobenzene with hydrazine hydrate in the presence of iron chloride and charcoal. This method provides an approach to the one-pot synthesis of 3,5-dinitroaniline, 1,3-diamino-5-nitrobenzene, or 1,3,5-triaminobenzene from 1,3,5-trinitrobenzene. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 904–905, May, 2006. |
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| Keywords: | 1,3,5-trinitrobenzene reduction nitro group hydrazine hydrate 3,5-dinitroaniline 1,3-diamino-5-nitrobenzene 1,3,5-triaminobenzene |
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