| Synthesis and Crystal Structure of 1＇-Methyl-4＇-（4-chlorophenyl）-1H-indole-3-spiro-2＇-pyrrolidine-3＇-spiro-4＂-（2＂-phenyloxazole）-2,5＂（3H,4＂H）-dione |
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| 作者姓名： | WEN Li-Rong LIU Peng LI Ming |
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| 作者单位： | College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology, Qingdao 266042, China |
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| 基金项目： | 国家自然科学基金，山东省自然科学基金 |
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| 摘 要： | The title compound （C26H20ClN3O3） has been synthesized by 1,3-dipolar cycloaddition reaction from isatin, sarcosine and （Z）-4-（4-chlorobenzylidene）-2-phenyloxazol-5（4H）-one through a one-pot procedure, and its structure was confirmed by IR, IH NMR, elemental analysis and single-crystal X-ray diffraction analysis. The crystal belongs to the triclinic system, space group PI, with a = 9.3903（19）, b = 11.398（2）, c = 12.603（3） A, α = 83.495（3）, β = 68.988（3）, γ = 67.178（3）^o, V= 1160.1（4）A^3 Z = 2, Mr= 457.90, Dc= 1.311 g/cm^3, p = 0.198 mm ^-1, F（000） = 476, the final R = 0.0489 and wR = 0.1144 for 3109 observed reflections with I 〉 2σ（I）.
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| 关 键 词： | 晶体结构 合成方法 吡咯烷 化学实验 |
| 收稿时间： | 2007-01-10 |
| 修稿时间： | 2007-04-16 |
Synthesis and Crystal Structure of 1'-Methyl-4'-(4-chlorophenyl)-1H-indole-3-spiro-2'-pyrrolidine-3'-spiro-4"-(2"-phenyloxazole)-2,5"(3H,4'H)-dione |
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| WEN Li-Rong LIU Peng LI Ming.Synthesis and Crystal Structure of 1''''-Methyl-4''''-(4-chlorophenyl)-1H-indole-3-spiro-2''''-pyrrolidine-3''''-spiro-4"-(2"-phenyloxazole)-2,5"(3H,4''''H)-dione[J].Chinese Journal of Structural Chemistry,2008,27(1):88-92. |
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| Authors: | WEN Li-Rong LIU Peng LI Ming |
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| Institution: | WEN Li-Rong, LIU Peng, LIMing (College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China) |
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| Abstract: | The title compound (C26H20C1H3O3) has been synthesized by 1,3-dipolar cycloaddi-tion reaction from isatin, sarcosine and (Z)-4-(4-chlorobenzylidene)-2-phenyloxazol-5(4H)-one through a one-pot procedure, and its structure was confirmed by IR, 1H NMR, elemental analysis and single-crystal X-ray diffraction analysis. The crystal belongs to the triclinic system, space group P1, with a = 9.3903(19), b = 11.398(2), c = 12.603(3) A, α = 83.495(3), β= 68.988(3), γ =67.178(3)°, V= 1160.1(4) A3, Z = 2, Mr= 457.90, Dc= 1.311 g/cm3,μ = 0.198 mm-1, F(000) = 476,the final R = 0.0489 and wR = 0.1144 for 3109 observed reflections with Ⅰ 20(Ⅰ). |
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| Keywords: | isatin oxazolidinone 1 3-dipolar cycloaddition MCRs crystal structure |
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