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Catalytic hydrodechlorination of chlorobenzene in liquide phase |
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| Authors: | José Luis Benítez and Gloria Del Angel |
| Institution: | (1) Departmento de Desarrollo de productos Químicos, Instituto Mexicano del Petróleo, Eje Central Norte Lázaro Cárdenas 152, A.P. 14-805, 07730, México, D.F.;(2) Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, P.O. Box 55-534, 09340 D.F., México |
| Abstract: | Catalytic hydrodechlorination of chlorobenzene (CB) was carried out in the liquid phase in a mixture of methanol/water (MeOH/H2O) at 30°C and 2kg/cm2 pressure. The reaction orders with respect to CB and H2 pressure were one and zero, respectively. Addition of NH4OH in the reaction produces a decrease in the activity (TOF). Solvent effect shows the following order of activity: H2O>MeOH/H2O>EtOH/H2O>MeOH. |
| Keywords: | hydrodechlorination chlorobenzene Pd/C solvent effect |
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