Conversion of hydrazones to alkyl chlorides under Swern oxidation conditions |
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| Authors: | Matthias Brewer |
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| Institution: | Department of Chemistry, The University of Vermont, 82 University Place, Burlington, VT 05405, USA |
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| Abstract: | The unsubstituted hydrazones derived from aromatic ketones and aldehydes were converted in high yield to the corresponding alkyl chlorides under Swern oxidation conditions. In this unusual oxidation/reduction sequence the substrate undergoes a net reduction under the well established Swern oxidation conditions. Unsubstituted hydrazones derived from cyclohexyl ketones returned elimination products. |
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