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Development of a chiral host system tunable via changes in a 21-column packing structure
Authors:Yoshitane Imai  Kakuhiro Kawaguchi  Reiko Kuroda  Yoshio Matsubara
Institution:a Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, Kowakae, Higashi-Osaka 577-8502, Japan
b JST ERATO-SORST Kuroda Chiromorphology Team, 4-7-6, Komaba, Meguro-ku, Tokyo 153-0041, Japan
c Department of Life Sciences, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan
Abstract:A tunable chiral host system was developed by the self-assembly of a chiral 21-column structure formed from (1R,2R)-1,2-diphenylethylenediamine and dicarboxylic acid. This host system can include guest molecules by changing the packing of a chiral 21-column enantioselectively.
Keywords:Chiral supramolecular complex  21-Column  Molecular recognition  Tunable host complex
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