Scandium(III) triflate-TMSCl promoted cyclization of aziridin-1-yl oximes to 5,6-dihydro-4H-[1,2,4]oxadiazines |
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| Authors: | Sung Yun Cho Seung Kyu Kang Jin Hee Ahn Jae Du Ha Joong-Kwon Choi |
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| Affiliation: | Bio-Organic Science Division, Korea Research Institute of Chemical Technology, 100 Jang-dong, Yuseong-gu, Daejeon 305-600, Republic of Korea |
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| Abstract: | A convenient and facile one-pot synthesis of 5,6-dihydro-4H-[1,2,4]oxadiazine is described. Treatment of aziridin-1-yl-oximes with Scandium(III) triflate readily afforded 5,6-dihydro-4H-[1,2,4]oxadiazine in the presence of chlorotrimethylsilane. |
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| Keywords: | Aziridinyl oxime Oxadiazine Scandium triflate |
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