Electrocatalytic multicomponent cyclization of an aldehyde, malononitrile and a malonate into 3-substituted-2,2-dicyanocyclopropane-1,1-dicarboxylate—the first one-pot synthesis of a cyclopropane ring from three different molecules期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Electrocatalytic multicomponent cyclization of an aldehyde, malononitrile and a malonate into 3-substituted-2,2-dicyanocyclopropane-1,1-dicarboxylate—the first one-pot synthesis of a cyclopropane ring from three different molecules

Authors:	Michail N. Elinson Sergey K. Feducovich Anatolii N. Vereshchagin Sergey V. Gorbunov Pavel A. Belyakov Gennady I. Nikishin

Affiliation:	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 119991 Moscow, Russia

Abstract:	Electrolysis of an aldehyde, malononitrile and a malonate in an alcohol in an undivided cell in the presence of sodium acetate-sodium halide as a double mediatory system results in the formation of 3-substituted-2,2-dicyanocyclopropane-1,1-dicarboxylates in 40-60% yields.

Keywords:	Electrolysis Electrocatalytic transformation Mediators Aldehydes Malononitrile Malonate Cyclopropanes
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