Total synthesis of the putative structure of the novel triquinane based sesquiterpenoid natural product dichomitol |
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Authors: | Goverdhan Mehta Kotapalli Pallavi |
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Affiliation: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India |
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Abstract: | A total synthesis of the recently reported triquinane natural product dichomitol, isolated from the fermentation broth of Dichomitus squalens, has been accomplished from the commercially available 1,5-cyclooctadiene through a series of unambiguous synthetic steps. A complete mismatch between the spectral characteristics of the synthetic product and that of the natural product warrants a revision of the structure of dichomitol. |
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