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Synthesis and manganese complexes of pentagonal bipyramidal ligands: N,N′-disubstituted pentaaza macrocycles
Authors:Wonchoul Park  Jin Ho Chung  Myoung Soo Lah
Affiliation:a Department of Applied Chemistry, Sejong University, Seoul 143-747, South Korea
b Department of Dermatology, Seoul National University College of Medicine, Seoul 110-744, South Korea
c Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do 426-791, South Korea
Abstract:Two novel heptadentate ligands, pentaaza macrocycles with two pendant xpyridyl and phenol groups, were prepared and the crystal structure of the manganese(II) complex of N,N′-bis(2-pyridylmethyl)-pentaaza macrocycle revealed a pentagonal bipyramidal geometry.
Keywords:Manganese   Pentagonal   Bipyramidal   Pentaaza   Macrocycle
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