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A novel synthesis of tetramesityldisilene
Authors:Cinzia Chiappe  Dieter Lenoir
Affiliation:a Dipartimento di Chimica Bioorganica e Biofarmacia, via Bonanno 33, 56100 Pisa, Italy
b Institut für Ökologische Chemie, Postfach 1129, D-85778 Neuherberg bei München, Germany
c Scuola Normale Superiore, Piazza dei Cavalieri 7, 56100 Pisa, Italy
Abstract:Dimesityldiclorosilane undergoes reductive coupling with potassium-graphite to afford a mixture of cyclic polysilanes in a high yield and purity; this mixture is quantitatively converted to the title compound by photochemical irradiation.
Keywords:Disilene   Polysilane   Cyclic
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