New modular P-chiral ligands for Rh-catalyzed asymmetric hydrogenation |
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| Authors: | Oleg G. Bondarev Richard Goddard |
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| Affiliation: | Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany |
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| Abstract: | New modular P-chiral ligands have been prepared from commercially available (S)-α,α-diphenylprolinol. With these new types of ligands, up to 95% ee was achieved in the Rh-catalyzed asymmetric hydrogenation of functionalized olefins. |
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| Keywords: | Asymmetric reactions Phosphorus ligands Rhodium Hydrogenation |
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