Synthesis,characterization and X-ray crystal structures of polyether and ethylene bridged bis(azolyl) platinum(II) complexes |
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| Authors: | Mairéad E Kelly Santiago Gómez-Ruiz Dirk Steinborn Christoph Wagner Harry Schmidt |
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| Institution: | 1.Institut für Chemie,Martin-Luther-Universit?t Halle-Wittenberg,Halle,Germany;2.Departamento de Química Inorgánica y Analítica,Universidad Rey Juan Carlos,Mostoles, Madrid,Spain |
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| Abstract: | The preparation of platinum(II) complexes of the types PtCl2{Y(CH2CH2O)
x
CH2CH2Y}] (Y: imidazol-1-yl, im; pyrazol-1-yl, pz or benzimidazol-1-yl, bim) and PtI2{im(CH2CH2O)
x
CH2CH2im}] with varying ligand backbone length (x between 0 and 3) is described. A new bis(pyrazol-1-yl) polyether compound, pz(CH2CH2O)2CH2CH2pz, is reported. Spectroscopic characterization of the complexes is discussed. Two crystal structures of the general formula
PtCl2{im(CH2CH2O)
x
CH2CH2im}] (x is 1 or 3) are also reported. |
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| Keywords: | |
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