An X-ray photoelectron spectroscopic study of some bis(diamine)-copper (II) complexes |
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| Affiliation: | 1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212100, PR China;2. School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212100, PR China |
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| Abstract: | XPS data for a series of octahedral copper(II) diamine tetrafluoroborate and perchlorate complexes are interpreted in the following terms; (i) the inductive effect of diamine substituents; (ii) the degree of cation-anion interaction; (iii) the effect of progressive increase in diamine chelate ring size; and (iv) the Jahn-Teller effect in these complexes. |
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