UV photoelectron spectra of adsorbed cyclopentadienyl |
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| Affiliation: | 1. Division of Physical Science and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia;2. Clean Combustion Research Center, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia;3. Division of Computer, Electrical, and Mathematical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia;1. Institute of Fluid Science, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577, Japan;2. International Combustion and Energy Laboratory, Far Eastern Federal University, 8 Suhanova St., Vladivostok 690950, Russia |
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| Abstract: | Angle resolved photoelectron spectra stimulated by synchrotron radiation are reported for cyclopentadienyl (Cp) adsorbed on Rh(III). Molecular orbital assignment of Cp derived photoemission bands is attempted by comparison with gas phase monometal-Cp complexes, MO calculations and by considering polarisation dependence and angular variation in the present oriented-molecule spectra. The spectra are discussed in terms of the intramolecular symmetry and of the symmetry of the total adsorption complex. |
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