Vapour pressure of binary,three-phase (S-L-V) systems and solubility |
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| Institution: | 1. State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;2. Collaborative Innovation Center of Chemical Science and Chemical Engineering of Tianjin, Tianjin University, China;3. Lionco Pharmaceutical Group, Haikou, Hainan 570100, China;1. Graduate Institute of Applied Mechanics, National Taiwan University, Taipei 10617, Taiwan;2. Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan;3. Graduate Institute of Photonics and Optoelectronics, Taipei 10617, Taiwan;4. Department of Electrical Engineering, National Taiwan University, Taipei 10617, Taiwan;1. Departamento de Física, Universidad de Sonora, Hermosillo, Sonora, C.P. 83000, Mexico;2. Posgrado en nanotecnología, Universidad de Sonora, Hermosillo, Sonora, C.P. 83000, Mexico |
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| Abstract: | Solubilities and vapour pressures along the solid-liquid equilibrium line for systems 2-t-butyl-4-methylphenol+benzene, 2-t-butyl-4-methylphenol+cyclohexane, 2,6-di-t-butyl-4-methylphenol+benzene, 2,6-di-t-butyl-4-methylphenol+cyclohexane and enthalpies of fusion for six phenols have been measured.The effect of specific interactions, leading to association, on solubilities and vapour pressures of 13 binary three-phase systems (S—L—V) has been discussed. Results of solubility prediction from vapour pressure measurements and vice versa are presented. |
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