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Theory of nuclear magnetic spin-rotational relaxation for asymmetric molecules
Institution:1. School of Chemistry, University of Southampton, Southampton, UK;2. Complex Carbohydrate Research Center, University of Georgia, Athens, GA 30602, United States
Abstract:A stochastic differential equation study of nuclear magnetic relaxation by spin-rotational interactions was successfully completed for spherical, symmetric rotator and linear molecules. This theory has now been extended to asymmetric rotator molecules by first establishing the conditions under which such an extension is mathematically feasible and then investigating the consequences of accepting these conditions.
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