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Probing the rotational disorder of molecules in plastic bicyclo[2.2.1]hept-2-ene with implanted muons
Affiliation:Dipartimento di Fisica, Università di Parma, I-43100 Parma, Italy;Physikalisch-Chemisches Institut der Universität Zürich, CH-8057 Zurich, Switzerland
Abstract:We report on μSR radical experiments on bicyclo[2.2.1]hept-2-ene, which demonstrate a dramatic change in the reorientational dynamics of the molecules throughout the plastic mesophase. The data might be related to some “order parameter” which is large at low temperature, while it is reduced almost by an order of magnitude (though it is still non-zero) close to the melting point.
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