Polymerization of ε-caprolactone initiated by stable salts. Initiation mechanism |
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| Authors: | N.E. Manolova I.B. Rashkov R.S. Velichkova I.M. Panayotov |
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| Affiliation: | Bulgarian Academy of Sciences, Central Laboratory for Polymers, Sofia 1040, Bulgaria |
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| Abstract: | The mechanism of initiation of ε-caprolactone polymerization by stable salts has been investigated. Gel permeation chromatography and 1H-NMR spectroscopy were used for determining the compositions of the reaction mixtures and of the polymers. It was established that the initiation proceeds by addition of the initiator to the monomer. |
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