Oxidative coupling of aromatic compounds with trimethylbenzylsilane by the action of MoCl5 |
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| Authors: | I. S. Akhrem N. M. Chistovalova D. V. Avetisyan V. F. Sizoi M. E. Vol'pin |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The benzylation of aromatic compounds was carried out efficiently under mild conditions by the action of trimethylbenzylsilane in the presence of MoCl5, AlCl3, or WCl6 with the formation of the corresponding diarylmethanes. The benzylation in the presence of MoCl5 conforms to behavior typical of electrophilic substitution.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1868–1870, August, 1987. |
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