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The gomberg-bachmann reaction of purines
Authors:Thomas C Mckenzie  Steven M Rolfes
Abstract:The reaction of adenine derivatives with isoamyl nitrite in anisole solution was re-investigated. The arylated products are a mixture of ortho, meta, and para-methoxyphenyl isomers with the ortho predominating. It is concluded that this is a typical free-radical arylation and that the 6-purinyl radical is a normal, well behaved aromatic radical.
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