|
|||||
|
|
Disproportionation reactions between alkyl and fluoroalkyl radicals. IV. Pentafluoroethyl and ethyl radicals |
|
| Authors: | G. O. Pritchard V. H. Kennedy G. M. Heldoorn M. L. Piasecki K. A. Johnson D. R. Golan |
| Abstract: | A new determination of the disproportionation/combination ratio for C2F5 and C2H5 radicals gives a value of Δ(C2F5, C2H5) = 0.24 ± 0.02, independent of temperature. The cross-combination ratio for the two radicals was found to increase with temperature and the significance of this is discussed in evaluating Δ. |
| Keywords: | |