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Disproportionation reactions between alkyl and fluoroalkyl radicals. IV. Pentafluoroethyl and ethyl radicals |
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| Authors: | G O Pritchard V H Kennedy G M Heldoorn M L Piasecki K A Johnson D R Golan |
| Abstract: | A new determination of the disproportionation/combination ratio for C2F5 and C2H5 radicals gives a value of Δ(C2F5, C2H5) = 0.24 ± 0.02, independent of temperature. The cross-combination ratio for the two radicals was found to increase with temperature and the significance of this is discussed in evaluating Δ. |
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