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Photopolymerization initiated by charge–transfer complex. X. Photopolymerization of methyl methacrylate with the use of isoquinoline–sulphur dioxide charge–transfer complex
Authors:Subasini Lenka  Padma L Nayak  Sanjay K Nayak
Abstract:Aqueous polymerization of methyl methacrylate in visible light was studied using isoquinoline–sulphur dioxide (IQ–SO2) charge–transfer complex as the photoinitiator. Analysis of kinetic and other data indicate that the polymerization proceed via a radical mechanism and the termination is dependent on the initiator concentration. Chain–termination via degradative chain (initiator) transfer appears to be predominant here.
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