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Simulation studies of branched polymer molecules
Authors:J E G Lipson
Abstract:Monte Carlo simulation results are presented for lattice models of uniform stars (one branch point of functionality f = 3), combs (two branch points, ? = 3,3) and brushes (two branch points ? = 3,4 and ? = 3,5). We estimate the critical exponent γ(?), the ratio g(?) = 〈Surn:x-wiley:01928651:media:JCC540080409:tex2gif-stack-1(?)〉/〈Surn:x-wiley:01928651:media:JCC540080409:tex2gif-stack-2(1)〉 (where 〈Surn:x-wiley:01928651:media:JCC540080409:tex2gif-stack-3(?)〉 is the mean-square radius of gyration of a structure having ? branches and N monomers), and the meansquare end-to-end branch lengths, as a function of the number and arrangement of branches. Comparisons with theoretical predictions and experimental data are made where possible, leading to a test of some predictions, and a suggestion concerning future experiments.
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