Metall-Komplexbildung von β-Hydroxythiophenderivaten III

The acidity constants of 2-acetyl-3-hydroxy-thiophene (III) and 3-acetyl-4-hydroxy-thiophene (IV) and the stability constants of their complexes with some bivalent metal ions have been determined. The stability of the chelates is discussed as a function of the respective bond orders of the α–β and β–β′ bonds of the thiophene ring.