Die Reaktion von Isonitrilen und Nitrilen mit Alkali- und Erdalkalimetallen |
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Authors: | W. Bü chner,R. Dufaux |
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Abstract: | Isocyanides RNC and the isomeric nitriles, RCN, reacting with alkali or alkaline earth metals in liquid ammonia undergo reductive fission to metal cyanides and carbanions R?. The latter are ammonolized to the corresponding hydrocarbons. |
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