|
|||||
|
|
ENANTIOSELECTIVE TOTAL SYNTHESES OF 13-ACETYL- 12-HYDROXY-PODOCARPANE- 8,11,13-TRIENE-7-ONE |
|
| Abstract: | ABSTRACT A enantioselective total synthetic route to (+)-13-acteyl-12-hydroxy-podocarpane-8,11,13-triene-7-one 1a and (?)-13-acetyl-12-hydroxy-podocarpane-8,11,13-triene-7-one 1b from (S)-(?)-α-cyclocitral 8a and (R)-(+)-α-cyclocitral 8b was developed. |
| Keywords: | |