Conversion of CO2 to Multi-carbon Compounds over a CoCO3 Supported Ru-Pt Catalyst Under Mild Conditions |
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Authors: | HUANG Jin CAI Yichen YU Yulv WANG Yuan |
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Institution: | 1. Beijing National Laboratory for Molecular Sciences, State Key Lab. for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;2. Sunan Institute for Molecular Engineering, Peking University, Changshu 215500, P. R. China |
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Abstract: | The catalytic hydrogenation of CO2 to multi-carbon compounds under mild conditions would not only provide value-added products, but also benefit for the reduction of CO2 emission if hydrogen derives from renewable energy sources. Herein, we report CoCO3 supported Ru and Pt nano-particles, which could catalyze hydrogenation of CO2 to produce higher hydrocarbons(C2-C26) and higher alcohols(C2OH-C6OH) at low temperatures of 80-130℃. The selectivity for C2+ compounds reached 81.1% at 80℃, which was the highest value reported so far. This work provides a promising catalyst for highly selective converting CO2 and H2 to C2+ compounds at low temperatures. |
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Keywords: | Heterogeneous catalyst Carbon dioxide Hydrogenation reaction Cobalt carbonate Multi-carbon compound |
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