Chlorokomplexe von Ti(III), V(III) und Cr(III) in Propandiol-1,2-carbonat und Trimethylphosphat |
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| Authors: | V. Gutmann A. Scherhaufer H. Czuba |
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| Affiliation: | (1) Institut für Anorganische Chemie der Technischen Hochschule Wien, Wien, Österreich |
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| Abstract: | Addition of chloride ions to the hexasolvated ions of Ti(III), V(III) and Cr(III) in propandiol-1,2-carbonate (PDC) and trimethylphosphate (TMP) may lead to the following complexes: [TiCl]2+ (inPDC), [TiCl2]+ (inTMP), TiCl3 (inPDC andTMP, low solubility inTMP), [TiCl4]? (inPDC andTMP?), [TiCl6]3? (inPDC); [VCl]2+ (inPDC andTMP), VCl3 (inPDC andTMP, low solubility inTMP), [VCl4]? (inPDC); [CrCl]2+ (inTMP), [CrCl2]+ (inPDC), CrCl3 (inPDC andTMP), [CrCl4]? (inPDC). |
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