| 利用氧化加成反应合成[Cu(C_6H_5COO)_2(C_5H_5N)_2(H_2O)] |
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| 引用本文： | 张廉奉. 利用氧化加成反应合成[Cu(C_6H_5COO)_2(C_5H_5N)_2(H_2O)][J]. 化学研究, 2000, 11(3): 34-36 |
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| 作者姓名： | 张廉奉 |
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| 作者单位： | 南阳教育学院化学系,南阳 473057 |
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| 摘 要： | 室温下 ,金属铜粉和过氧化苯甲酰进行氧化加成反应合成了铜化合物 [Cu(C6H5COO) 2 (C5H5N) 2 (H2 O) ](1 )。通过元素分析、电导、红外光谱等方法对配合物进行了表征 ,并经X 射线单晶结构分析确定了配合物的结构 ,晶体属单斜晶系 ,空间群Cc ,a =0 .60 78(4) ,b =1 .5879(4) ,c =2 .30 91 (3)nm ,β =97.61 (2 )°,Z =4,V =2 .2 0 91nm3,R =0 .0 30 7,中心铜原子由单齿配位的苯甲酸根的氧原子和吡啶的氮原子及来自水分子的氧原子形成四方锥配位结构。
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| 关 键 词： | 铜 配合物 氧化加成 |
| 文章编号： | 1008-1011(2000)03-0034-03 |
| 修稿时间： | 2000-02-21 |
Synthesis of bis(Benzoxy)-(Water)-bis(Pydine)Copperby Oxidative Addition Reaction |
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| ZHANG Lian feng. Synthesis of bis(Benzoxy)-(Water)-bis(Pydine)Copperby Oxidative Addition Reaction[J]. Chemical Research, 2000, 11(3): 34-36 |
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| Authors: | ZHANG Lian feng |
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| Abstract: | At room temperature, the copper(Ⅱ) complex has been prepared by oxidative addition reaction between metallic copper powder and dibenzoyl peroxide.The title complex was also characterized by elemental analysis,IR spectra and conductivity properties.Crystals (1) are monoclinic,space group Cc,with cell parameters a=0.6078(4),b=1.5879(4),c=2.3091(3) nm, β =97.61(2)°, Z =4, V =2.2091 nm 3, R =0.0307.Each copper(Ⅱ) ion is coordinated by two monodentate benzoate,pyridine and oxygen atom from water molecule to form square pyramid coordination structure. |
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| Keywords: | copper complex oxidative addition |
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