Guayulin B |
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Authors: | José Castañeda-Acosta Frank R. Fronczek Nikolaus H. Fischer |
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Affiliation: | (1) Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana, 70803 |
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Abstract: | The sesquiterpene guayulin B, C23H30O3, 1, crystallizes with two independent molecules in monoclinic space group P21 with a = 18.099 (1), b = 6.0649(6), c = 19.126(1) Å, = 100.82(1)°, V = 2062.1(5) Å3, and Z = 4. The double bonds of the cyclodecadiene ring are E, both methyl groups on the 10-membered ring are -oriented. The cyclopropane ring at C6 and C7 also has the orientation, while the anisoyloxy group is oriented . The 10-membered rings of the two independent molecules have the same conformation as that of guayulin A. |
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Keywords: | Guayulin B sesquiterpene bicyclogermacradiene |
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