Hydrogen tunneling in biology. |
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Authors: | A Kohen J P Klinman |
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Institution: | Departments of Chemistry and Molecular and Cell Biology, University of California at Berkeley, Berkeley, CA 94720, USA. |
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Abstract: | The mechanistic details of hydrogen transfer in biological systems are not fully understood. The traditional approach has been to use semiclassical transition-state theory. This theory cannot explain many experimental findings, however, so different approaches that emphasize the importance of quantum mechanics and dynamic effects should also be considered. |
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