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On the Behavior of [Zn(Propyltetrazole)6](BF4)2 Single Crystal Under High-Vacuum Conditions
Authors:T. Marek  Cs. Szeles  G. Molnár  J. Borossay  A. Vértes  K. G. Lynn
Affiliation:(1) Department of Nuclear Chemistry, Eötvös Loránd University, P.O.Box 32, H-1518 Budapest, Hungary;(2) Department of General and Inorganic Chemistry, Eötvös Loránd University, P.O.Box 32, H-1518 Budapest, Hungary;(3) Department of Nuclear Chemistry, Eötvös Loránd University, P.O. Box 32, H-1518 Budapest, Hungary;(4) Departments of Material Science and Physics, Brookhaven National Laboratory, Upton, NY, USA
Abstract:We studied the long-term (190 hours) behaviour of [Zn(propyltetrazole)6](BF4)2 single crystal under high-vacuum (HV) conditions (10–8 torr) with a depth-sensitive technique of positron annihilation spectroscopy (PAS). The obtained data indicate the slow formation of a new near-surface structure which is formed by the decomposition of the [Zn(propyltetrazole)6]2+ ions. The assumption of such a decomposition process was confirmed by additional mass spectroscopic measurements.
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