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On the Behavior of [Zn(Propyltetrazole)6](BF4)2 Single Crystal Under High-Vacuum Conditions |
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| Authors: | T. Marek Cs. Szeles G. Molnár J. Borossay A. Vértes K. G. Lynn |
| Affiliation: | (1) Department of Nuclear Chemistry, Eötvös Loránd University, P.O.Box 32, H-1518 Budapest, Hungary;(2) Department of General and Inorganic Chemistry, Eötvös Loránd University, P.O.Box 32, H-1518 Budapest, Hungary;(3) Department of Nuclear Chemistry, Eötvös Loránd University, P.O. Box 32, H-1518 Budapest, Hungary;(4) Departments of Material Science and Physics, Brookhaven National Laboratory, Upton, NY, USA |
| Abstract: | We studied the long-term (190 hours) behaviour of [Zn(propyltetrazole)6](BF4)2 single crystal under high-vacuum (HV) conditions (10–8 torr) with a depth-sensitive technique of positron annihilation spectroscopy (PAS). The obtained data indicate the slow formation of a new near-surface structure which is formed by the decomposition of the [Zn(propyltetrazole)6]2+ ions. The assumption of such a decomposition process was confirmed by additional mass spectroscopic measurements. |
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