| 应用群论分析甲烷的红外和拉曼光谱特征 |
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| 引用本文： | 谷开慧,邢淑芝,解玉鹏,韩颖,郭明,侯丽新,孙晓冰.应用群论分析甲烷的红外和拉曼光谱特征[J].大学物理实验,2012(3):5-6. |
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| 作者姓名： | 谷开慧 邢淑芝 解玉鹏 韩颖 郭明 侯丽新 孙晓冰 |
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| 作者单位： | 1. 长春理工大学,吉林长春130012
2. 吉林化工学院,吉林吉林132022 |
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| 基金项目： | 吉林省教育厅资助项目(吉教科合子2010第491号),吉林省教育厅资助项目(吉教科合字2011第357号) |
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| 摘 要： | 应用群论的方法构造CH4的简正坐标从而组合它的9个简正振动模式,根据红外光谱和拉曼光谱的选择定则分析CH4简正振动模式得出CH4分子的红外和拉曼光谱特征,采用群论方法使我们的计算大大简化.
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| 关 键 词： | 甲烷 投影算符 简正坐标 简正振动模式 |
The Study of Infrared and Raman Spectrum Characteristic of CH4 by Group Theory |
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| GU Kai-hui,XING Shu-zhi,XIE Yu-peng,HAN ying,GUO Ming,HOU li-xin,SUN Xiao-bing.The Study of Infrared and Raman Spectrum Characteristic of CH4 by Group Theory[J].Physical Experiment of College,2012(3):5-6. |
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| Authors: | GU Kai-hui XING Shu-zhi XIE Yu-peng HAN ying GUO Ming HOU li-xin SUN Xiao-bing |
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| Institution: | 1(1.Changchun University of Science and Technology,Jilin,Changchun 130012;2.Jilin Institute of Chemical Technology,Jilin,Jilin 132013) |
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| Abstract: | Application of the method group theory to structure and analyse 9 normal vibration modes.According to both infrared and Raman spectrum select formula,we can get the spectral characteristic of CH4.Group theory plays a important role in this paper,using it we can do our best to ease the calculation. |
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| Keywords: | projection operator normal coordinate normal vibration mode |
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