Electrochemical behaviour of 3,8-difluorobenzo[c]cinnoline at mercury electrode |
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Authors: | Durmu? Z Solak A O Durmu? S Kiliç E |
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Institution: | Department of Chemistry, Ankara University, Tando?an 06100, Ankara, Turkey. |
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Abstract: | Voltametric and coulometric methods have been used to study the electroanalytical behaviour of 3,8-difluorobenzoc]cinnoline. The number of electrons transferred, the wave characteristics, diffusion coefficient and reversibility of the reactions have been investigated in ethyl alcohol-BR. Adsorption of the molecule on the surface of the mercury drop electrode was analyzed and this phenomena was exploited to calculate the diffusion coefficient of 3,8-difluorobenzoc]cinnoline. A mechanism for the electrode reaction was proposed. |
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