Crystal and molecular structure of 1-methyl-2,3,5,6-tetraphenylpiperidin-4-ol,C30H29NO |
| |
| Authors: | V Parthasarathi Paul T Beurskens H J J Behm S Garcia-Granda M Krishna Pillay |
| |
| Institution: | (1) Crystallography Laboratory, University of Nijmegen, Toernooiveld, 6525 ED Nijmegen, The Netherlands;(2) Department of Chemistry, Bharathidasan University, 620023 Tiruchirapalli, India |
| |
| Abstract: | The structure of the the title compound, C30H29NO, was determined by X-rays.M
r
=419.57, triclinic, space groupP1,a=5.8922(12),b=8.5855(11),c=12.2216(20) Å, =78.145(12)°, =79.181(15)°,  =76.108(14)°,V
c
=581.1(1) Å3,Z=1,D
x
=1.199 Mg m–3. CuK radiation (graphite crystal monochromator,  =1.54184 Å), (CuK)=5.17 cm–1,T=290K. Final conventionalR-factor=0.039,R
w
=0.042 for 2795 observed reflections and 377 variables. The structure was solved usingMultan andDirdif. With a view to determining the conformational preference of the piperidine ring when it is highly sustituted with a bulky group like the phenyl group, the present X-ray investigation was undertaken. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
