Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex |
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| Authors: | Ishizuka Tomoya Tobita Kengo Yano Yuichi Shiota Yoshihito Yoshizawa Kazunari Fukuzumi Shunichi Kojima Takahiko |
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| Institution: | Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan. |
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| Abstract: | A heterodinuclear complex based on a Ru(II)-TPA TPA = tris(2-pyridylmethyl)amine] complex having a peripheral Cu(II)(bpy)(2) (bpy = 2,2'-bipyridine) group bonded through an amide linkage displayed reversible intramolecular electron transfer between the Ru and Cu complex units that can be controlled by protonation and deprotonation of the bridging amide moiety. |
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